Transporting Giggenbach Sampling Flasks by Aircraft IAVCEI
CCVG
IUGG
Updated !! Version 2

Here are some useful tips when considering the transport of NaOH filled Giggenbach flasks overseas (crossing country borders) by aircraft.
This is information on how to ship them without breaking any laws (fines on airports are on the order of 27 000 to up to 500 000 US$ for the airline if caught ... and they bill you for that).
These tips are intended for NaOH solution inside Giggenbach bottles only, not TMAH, KOH, NaOH pills, or others.

Introduction
The domestic air shipping rules are very similar in most countries, and if you stick to the same shipper to and from you can usually assume the same process both ways. For instance, in the U.S.A., 49CFR (version 2004) regulates dangerous goods shipping (see sections 171-173, 175, 178; for 2003 see here), your country might have similar laws. You have to always consider the laws of both the shipping and receiving country.

International dangerous goods shipping (packing, labelling, shipping papers, loading, transport, etc) is regulated by the international body IATA (International Air Transport Association) and the rules are very similar to 49CFR. Air carriers will usually only accept shipments that are packed and labelled according to IATA rules, and if you are a so-called known shipper (trusted customer with a DG contract).

You can usually not just drop off/pick up your package at a branch location but you need either an institution or company to receive the shipment for you, and for the return, pack and ship it for you at your field location (e.g., a shipping forwarder that does DG packing/shipping). The same applies if you ship bottles somewhere abroad for analysis. These companies that issue shipping papers and do the packingand forwarding but are not air carriers are also termed Indirect Air Carriers (IAC), or shipping/freight forwarders.

Note: transporting Hazardous Materials on roads / by vehicle is (in most countries) also regulated.

Shipping & Packing
Contact the shipper months in advance if you use them the first time. Carriers that ship hazardous cargo on a contract basis (not your small packages contract of your institution) are for instance UPS and American Airlines Cargo - FedEx does not ship DG internationally.

AA Cargo has experience with scientific hazardous cargo. It takes up to 2 months to become a known shipper in order to be able to ship with them (or any other cargo carrier). See details below on how to become a known shipper. You can also use UPS, they have a HazMat group in every country (call UPS and ask for the number of the DG group).

Talk to the environmental health & safety people at your University/Institution, or your University's chemical waste disposal staff (and/or HazMat) about the shipment, insurance and liability issues. 

For U.S. regulations on any hazardous material, look at 49CFR, subpart B first (2003, scroll to page 252 for sodium hydroxide solution).

Codes

AACargo American Airlines Cargo
(air carrier)
IATA International Air Transport Association
(organization, airlines)
ICAO International Civil Aviation Organization (U.N. body)
CFR Code of Federal Regulations (law, U.S.)
DG Dangerous Goods (term)
DOT Department of Transportation
(government body, U.S.)
FAA Federal Aviation Administration
(government body, U.S.)
FedEx Federal Express (air carrier)
HazMat Hazardous Materials (regulatory term)
IAC
Indirect Air Carrier (TSA / FAA administrative term)
MSDS Material Safety Data Sheet (term)
NaOH Sodium Hydroxide (name)
OSHA Occupational Safety & Health Administration (workplace safety)
PAL Precise Account Locator (administrative term)
PG Packaging Group (regulatory term)
TSA Transport Security Administration
UPS United Parcel Service (air carrier)
1H1 dangerous goods packing container type
(plastic pail, non-removable lid)
4G DG carton packing type
(regulatory term)
Packing personnel
Training:
an IATA certified hazardous material packer must do the packing.
You can possibly obtain such a certificate yourself by attending a hazardous materials IATA course at your university/institute if they offer one.

A normal University chemical safety and hazardous waste handling course is not enough.
These courses may in some institutions be free of charge for employees, however at ASU they cost around 300 US$, private companies specialized in training charge about 450 US$.

If the shipper accepts you as a packer or not is not guaranteed, and you should consult with both your institution's HazMat people and the cargo representative of the cargo company you use.

See 49CFR 172.704 if you qualify as a hazardous materials cargo packer.

Packing material
(see 49CFR 178)
We suggest packing group 2: inner container, absorbent, outer container, labels, paperwork
  • inner container: "glass ampoules" or "glass receptacle" (Giggenbach-bottles) with a high-vacuum stopcock;
  • absorbent: flakes of vermiculite (mica);
  • outer packing: a 1H1 plastic drum - the same ones you often see for example for paint on construction sites, tall white plastic buckets (pail) with several enforcement plastic rings near the top and a handle) with one-way sealable lid (cost: ca. US$3); get an extra lid per pail for the return shipment. Do not use screw top lids! See 49CFR 178.509 and links below;
  • marking: (note marking is not labeling!)
    • orientation/up arrows (can be a label);
    • proper shipping name and UN ID# (see HazMat table, UN 1824); 49CFR 172.
  • labeling: must be according to DOT rules (check with hazardous material staff).
    • note: a label is not a placard;
    • hint: NaOH (aq., conc.) packed in this manner is a class 8 liquid (corrosive), UN 1824, PG2, according to 49CFR.
  • shipping papers: for what you need per pial or pack, see 49CFR 172.201-205:
    • 4 MSDS for conc. NaOH solution;
    • 1 Air Waybill (e.g., American Airlines Cargo Air Waybill - get one at the drop-off location);
    • 1 Cargo "IAC Known Shipper Acceptance Info" form (get or fill out at drop-off location, bring ID);
    • other documents as specified by 49CFR.

As an additional (optional) measure, the bottles at ASU (where this shipping method is used) are packed in tennis ball saver containers (max. cylindrical OD of bottle & valve: 60 mm).

Ship bottles as cargo
  • Never ship NaOH in luggage or as "water samples".
  • Do not show up at the airport without having talked to airline cargo personnel in advance;
  • Drop off your package well before the plane takes off but try to drop it off on the same day as the plane departs. Airlines are not allowed to store it hazardous materials for long, so pick up package soon after you arrive at destination. If possible put your package on the same plane that you fly on. With AACargo there is usually enoughtime if you drop it off 1 hour before departure (e.g., after you have checked in yourself, also internationally);
  • For AACargo, find the shipper's cargo drop-off location in the cargo section of your airport beforehand.

The "known shipper" issue
With most air carriers, you can only ship cargo (e.g., using AA Cargo) if you are a known shipper.

How to become one... this is info based on experience with American Airlines Cargo. Procedures at other airlines may vary. You can only become a known shipper if they approve your PAL application, and visit you:

Download the registration form for a PAL (Precise Account Locator) number on the aacargo AACargo web site and call them. They usually sit on it for a month and then contact you. Be persistent and keep calling, try to talk to a real person. Once you have applied for a PAL, there will be background checks required by the Dept of homeland security, FBI & CIA. This takes time... they want to know that your university/institute really exists and after giving you a PAL, will send someone out to visit you/the Dept. Some more information can be found here.

You receive your PAL by mail or fax, which includes a shipping contract on the same form (this is not for an actual physical shipment but to establish a business relationship). there are background checks required by the DHS, FBI & CIA. This takes time... they want to know that your University/Institute really exists and will send someone out to visit you/the Dept. Letterhead certificates from your institution's president won't help, but former UPS and FedEx bills in your Department's name will do - they will ask for that before they send the person out to meet you/check up on you. You will have to fax or mail this form back, and provide the evidence indicated above. You can only ship AA cargo if you are a known shipper .

If that evidence is sufficient, you will be contacted to make an appointment for a business inspection with an AACargo representative. During that visit, the verified known shipper validation form is filled out and signed. Make very sure you have a photocopy! The next step is packing & shipping.
Links
Agencies
HazMat shippers
Pails & packing

Cargo limitations
Quantity:
if it goes to/from the US, the total per cargo airplane is up to 2 liters of concentrated NaOH (passenger planes: 1 liter).

You should prepare packages that are below 1 L
because not in every case will you be able to get cargo aircraft transport.
(e.g., 70 mL NaOH before sampling, 150 mL after sampling, so you can fit 6 bottles into one pack)

It can also take around ten days only between Europe and North America, let alone less frequented routes...

If you want to see how nit-picky it can get, see this example of the transport of Infectious Substances and Diagnostic Samples.
Note the fines here - they are significantly lower than for sodium hydroxide.

Authors / contact
Information compiled by:

Florian M. Schwandner (ASU)
and
Toby Fischer (UNM),

1st uploaded: January 2005;

updates:
April 2005.

Disclaimer
This site provides information about the regulations designed to help scientists to transport NaOH-filled Giggenbach bottles safely and according to air cargo rules.

No responsibility, accuracy or liability is assumed by the authors or IAVCEI. No third party interest.

We thank Bill Lorentz (AA Cargo), Terry Hamner (UPS) and Henry Walsh (ASU) for advice.